Zhou, J.S.; Reining, L.; Nicolaou, A.; Bendounan, A.; Ruotsalainen, K.; Vanzini, M.; Kas, J. J.; Rehr, J. J.; Muntwiler, M.; Strocov, V.N.; Sirotti, F.; Gatti, M.: Unraveling intrinsic correlation effects with angle-resolved photoemission spectroscopy. Proceedings of the National Academy of Sciences of the United States of America : PNAS 117 (2020), p. 28596-28602
10.1073/pnas.2012625117
Open Access Version (externer Anbieter)
Abstract:
Interaction effects can change materials properties in intriguing ways, and they have, in general, a huge impact on electronic spectra. In particular, satellites in photoemission spectra are pure many-body effects, and their study is of increasing interest in both experiment and theory. However, the intrinsic spectral function is only a part of a measured spectrum, and it is notoriously difficult to extract this information, even for simple metals. Our joint experimental and theoretical study of the prototypical simple metal aluminum demonstrates how intrinsic satellite spectra can be extracted from measured data using angular resolution in photoemission. A nondispersing satellite is detected and explained by electron–electron interactions and the thermal motion of the atoms. Additional nondispersing intensity comes from the inelastic scattering of the outgoing photoelectron. The ideal intrinsic spectral function, instead, has satellites that disperse both in energy and in shape. Theory and the information extracted from experiment describe these features with very good agreement.